Showing 2 results for Adsorption Isotherm
N Samadani, V Jodaeian,
Volume 14, Issue 4 (6-2015)
Abstract
The aim of this study is to investigate the possibility of the using rice bran as a natural and suitable adsorbent for the removal of formic acid whose is an organic acid from liquid solution and the effect of various parameters such as adsorbent dose, initial concentration adsorbate, temperature and time on the adsorption process and determination of adsorption isotherm constants. Removal of organic acids from liquid solutions is an important environmental challenge. Batch adsorption experiments showed that the adsorption increased with the increasing of the amount of adsorbent, initial concentration of adsorbate and decreasing temperature and adsorption process is reached the equilibrium state after one hour. The adsorption data was analyzed using the various isotherm models. From these various isotherm models, the adsorption process obeys the Langmuir and Freundlich adsorption isotherms. The results show a good agreement with both methods.The average amount of adsorbate per 3 degrees of freedom and confidence 95% ، 10.39±0.095 ، is obtained
Fatemeh Talebi Khalilmahalleh, Reza Marandi,
Volume 14, Issue 4 (6-2015)
Abstract
The environmental pollution of harmful toxic metals is one of the important issues in the world today. Nickel is one of the toxic heavy metals which if enters into the human body in high concentrations it will cause skin allergy, heart disease and various cancers. Therefore, there is need to remove Nickel from industrial wastewater. The purpose of this study was firstly to remove nickel from aqueous solutions with synthesized activated carbon from carrot remains and secondly to investigate the effect of variations of the adsorbent particle sizes on the equilibrium time and the removal efficiency. For this purpose, adsorption of Ni (II) ions on the adsorbent was studied in a batch process. Firstly, the activated carbon was prepared from carrot remains with particle sizes between 37 and 300 micrometers. The results showed that the maximum absorption efficiency occurs (100%) at pH of 6. Moreover, it was shown that with decreasing the adsorbent size from 300 to 37 µm, the equilibrium time will decreases from 130 to 20 min. Experimental data was best fitted onto pseudo-second order model. Langmuir and Freundlich isotherms equation were used to fit the adsorption isotherms. It is evident from this study that activated carbon is a suitable material for the uptake of Ni (II) from aqueous solutions.
